DropDownList绑定数据源的情况下把Select放在首位(AppendDataBoundItems="True")
<asp:DropDownList ID="ddlStore" runat="server" DataSourceID="SqlDataSource2" DataTextField="StoreName" DataValueField="StoreId" AppendDataBoundItems="True">
<asp:ListItem Value="" Selected="True">--Select--</asp:ListItem>
</asp:DropDownList>