ORA-32004错误原因：由于在初始化参数文件中存在一些在该Oracle版本中不支持的一些参数，因此会在启动的时候提示这个错误，但不影响系统的使用。既然发现有这个问题存在就应该解决了。解决步骤如下：
（1）查看alert日志，从中搜索“deprecated(意思是弃用)"，找到提示的哪个存在于spfile中弃用的参数
（2）进入sqlplus，使用alter system reset log_archive_start scope=spfile sid='*';(注：这里使用的参数为log_archive_start)
(3)重启数据库，即可正常。
因此需要关注下Oracle10G中不再支持的参数。
下面是Oracle 10gR2不再支持的参数
* ENQUEUE_RESOURCES (undocumented in 10gR2)
* DBLINK_ENCRYPT_LOGIN
* HASH_JOIN_ENABLED (undocumented parameter)
* LOG_PARALLELISM (undocumented parameter)
* MAX_ROLLBACK_SEGMENTS
* MTS_CIRCUITS (this is replaced by CIRCUITS)
* MTS_DISPATCHERS (this is replaced by DISPATCHERS)
* MTS_LISTENER_ADDRESS
* MTS_MAX_DISPATCHERS (this is replaced by MAX_DISPATCHERS)
* MTS_MAX_SERVERS (this is replaced by MAX_SHARED_SERVERS)
* MTS_MULTIPLE_LISTENERS
* MTS_SERVERS (this is replaced by SHARED_SERVERS)
* MTS_SERVICE
* MTS_SESSIONS (this is replaced by SHARED_SERVER_SESSIONS)
* OPTIMIZER_MAX_PERMUTATIONS (undocumented parameter)
* ORACLE_TRACE_COLLECTION_NAME
* ORACLE_TRACE_COLLECTION_PATH
* ORACLE_TRACE_COLLECTION_SIZE
* ORACLE_TRACE_ENABLE
* ORACLE_TRACE_FACILITY_NAME
* ORACLE_TRACE_FACILITY_PATH
* PARTITION_VIEW_ENABLED (undocumented parameter)
* PLSQL_NATIVE_C_COMPILER
* PLSQL_NATIVE_LINKER
* PLSQL_NATIVE_MAKE_FILE_NAME
* PLSQL_NATIVE_MAKE_UTILITY
* ROW_LOCKING (undocumented parameter)
* SERIALIZABLE (undocumented parameter)
* TRANSACTION_AUDITING (undocumented parameter)
* UNDO_SUPPRESS_ERRORS
6.下面是Oracle 10gR2不建议使用参数
* LOGMNR_MAX_PERSISTENT_SESSIONS (Oracle Streams uses it)
* MAX_COMMIT_PROPAGATION_DELAY
* REMOTE_ARCHIVE_ENABLE
* SERIAL_REUSE
* SQL_TRACE
* BUFFER_POOL_KEEP [replaced by DB_KEEP_CACHE_SIZE]
* BUFFER_POOL_RECYCLE [replaced by DB_RECYCLE_CACHE_SIZE]
* GLOBAL_CONTEXT_POOL_SIZE
* LOCK_NAME_SPACE
* LOG_ARCHIVE_START
* MAX_ENABLED_ROLES
* PARALLEL_AUTOMATIC_TUNING
* PLSQL_COMPILER_FLAGS [replaced by PLSQL_CODE_TYPE and PLSQL_DEBUG]
